Synthesis of Benzo［j］fluoranthene at Room Temperature
ZHANG Qiang, YANG Hai-tao, XU Qiong， TIAN Guang-hui， JI Xiao-hui， MIN Suo-tian， GE Hong-guang
Key Laboratory for Catalytic basis and Application of Shanxi Province, School of Chemistry and Environmental Science, Shanxi University of Technology, Hanzhong 723001, China
Abstract：4,4′-（Ｐhenylmethylene）bis(1-butoxynaphthalene)（2） was synthesized by Friedel-Crafts reaction of 1-butoxynaphthalene with benzaldehyde using FeCl3 as the catalyst. 5,12-Dibutoxy benzo［j］fluoranthene(3) was obtained by Scholl reaction of 2. 2 and 3 were novel compounds. The structures were characterized by 1H NMR， 13C NMR， MALDI-TOF-MS and X-ray single crystal diffraction. ３belongs to monoclinic system， space group Ccwith a=16.606 2(15) ， b=14.395 5(15) ， c=10.185 9(9) ， β=116.338(9)°， V=2 182.2(4) 3.
张强， 杨海涛， 许琼， 田光辉， 季晓晖， 闵锁田， 葛红光. 一种室温条件下合成苯并［j］荧蒽的新方法[J]. 合成化学, 2015, 23(11): 1049-1052.
ZHANG Qiang, YANG Hai-tao, XU Qiong， TIAN Guang-hui， JI Xiao-hui， MIN Suo-tian， GE Hong-guang. Synthesis of Benzo［j］fluoranthene at Room Temperature. Chinese Journal of Synthetic Chemistry, 2015, 23(11): 1049-1052.
2015, Vol. 23 
