Preparation and Hg2+ Adsorption Properties of Thiol Functionalized Mesoporous Materials
SONG Bo1,2, LI Yun-ping2, WANG Chun2, WANG An1
1. College of Architecture and Environment, Sichuan University, Chengdu 610065, China; 2. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China
Abstract：A series of thiol functionalized mesoporous materials(SBA-SH-x) with different thiol ratio［x=n(MPTES)/n(TEOS+MPTES)］ were prepared by copolymerization of hydrolyzed TEOS and MPTES in acid condition, using tri-block non-ionic surfactant P123 as template. The structures and properties were characterized by FT-IR, elemental analysis, SEM, TEM, small angle X-ray and N2 adsorptiondesorption. The results showed that x＜10%, SBA-SH-x were hexagonal p6mm mesophase; 10%＜x＜15%, SBA-SH-x were cubic Ia3d mesophase; x＞20%, SBA-SH-x were in disorder structure. Further increase of thiol contents resulted in slatted or non-mesoporous materials. The results of Hg2+ adsorption in water indicated that SBA-SH-10 and SBA-SH-15 exhibited good adsorption properties.
宋波， 李云萍， 王淳， 王安. 表面高巯基功能化介孔材料的制备及对Hg2+的吸附性能[J]. 合成化学, 2016, 24(2): 124-129.
SONG Bo, LI Yun-ping, WANG Chun, WANG An. Preparation and Hg2+ Adsorption Properties of Thiol Functionalized Mesoporous Materials. Chinese Journal of Synthetic Chemistry, 2016, 24(2): 124-129.
2016, Vol. 24 
