Abstract：Two novel flexible tert-butylsulfinyl-NH-olefine tridentate ligands(4a, 4b) were synthesized by condensation and reduction starting with 2-tert-butylsulfinylbenzylamine and 2-vinyl-benzaldehyde or 2-styrylphenyl-benzaldehyde. The structures were characterized by 1H NMR， 13C NMR and HR-MS. The catalytic activities of 4a and 4b with iridium in transfer hydrogenation reaction of acetophenone were investigated. The conversion were 94% and 51%, respectively.
林泽超, 唐磊, 黄晴菲, 王启卫, 邓金根. 新型“NH-叔丁亚砜-烯”配体的合成及其在转移氢化反应中的应用[J]. 合成化学, 2016, 24(4): 342-346.
LIN Zhe-chao, TANG Lei, HUANG Qing-fei, WANG Qi-wei, DENG Jin-gen. Synthesis of Novel Sulfinyl-NH-olefine Ligands and Their Application in Transfer Hydrogenation Reaction. Chinese Journal of Synthetic Chemistry, 2016, 24(4): 342-346.
2016, Vol. 24 
