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| Synthesis of Benzo［j］fluoranthene at Room Temperature |
| ZHANG Qiang, YANG Hai-tao, XU Qiong， TIAN Guang-hui， JI Xiao-hui， MIN Suo-tian， GE Hong-guang |
| Key Laboratory for Catalytic basis and Application of Shanxi Province, School of Chemistry and Environmental Science, Shanxi University of Technology, Hanzhong 723001, China |
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Abstract 4,4′-（Ｐhenylmethylene）bis(1-butoxynaphthalene)（2） was synthesized by Friedel-Crafts reaction of 1-butoxynaphthalene with benzaldehyde using FeCl3 as the catalyst. 5,12-Dibutoxy benzo［j］fluoranthene(3) was obtained by Scholl reaction of 2. 2 and 3 were novel compounds. The structures were characterized by 1H NMR， 13C NMR， MALDI-TOF-MS and X-ray single crystal diffraction. ３belongs to monoclinic system， space group Ccwith a=16.606 2(15) ， b=14.395 5(15) ， c=10.185 9(9) ， β=116.338(9)°， V=2 182.2(4) 3.
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Received: 25 August 2018
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| [1] |
. [J]. Chinese Journal of Synthetic Chemistry, 2015, 23(12): 0-0. |
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2015, Vol. 23 
