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| Synthesis of Novel (Z)-ethyl 2-［(2-iodophenoxy)(aryl)methyl］but-2-enoate Compounds |
| PAN Cheng-min1,2, YANG Jian-guo2, MO Han-jie2, GAO Jian-rong1 |
| 1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China;2. School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, China |
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Abstract Ten novel (Z)-ethyl ［(2-iodophenoxy)(phenyl)methyl)but-2-enoate compounds in yields of 79%~98% were synthesized by β′-nucleophilic addition of phenols with allenes in N2 using triphenylphosphine as the catalyst and benzene as the solvent. The structures were characterized by 1H NMR, 13C NMR and ESI-MS.
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Received: 12 April 2015
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2015, Vol. 23 
